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Since no reliable historically dated artifacts exist which are older than 5,000 years, it has not been possible to determine the relationship of radiocarbon years to calendar years for objects which yield dates of tens of thousands of radiocarbon years.
Thus, it is possible (and, given the Flood, probable) that materials which give radiocarbon dates of tens of thousands of radiocarbon years could have true ages of many fewer calendar years. The shells of live freshwater clams have been radiocarbon dated in excess of 1600 years old, clearly showing that the radiocarbon dating technique is not valid.
This gives the clam shell an artificially old radiocarbon age.
This problem, known as the "," is not of very great practical importance for radiocarbon dating since most of the artifacts which are useful for radiocarbon dating purposes and are of interest to archaeology derive from terrestrial organisms which ultimately obtain their carbon atoms from air, not the water. Samples of coal have been found with radiocarbon ages of only 20,000 radiocarbon years or less, thus proving the recent origin of fossil fuels, probably in the Flood.
Measurements made using specially designed, more elaborate apparatus and more astute sampling-handling techniques have yielded radiocarbon ages for anthracite greater than 70,000 radiocarbon years, the sensitivity limit of this equipment. Continuous series of tree-ring dated wood samples have been obtained for roughly the past 10,000 years which give the approximate correct radiocarbon age, demonstrating the general validity of the conventional radiocarbon dating technique.
Several long tree-ring chronologies have been constructed specifically for use in calibrating the radiocarbon time scale.
Other radiometric dating methods such as potassium-argon or rubidium-strontium are used for such purposes by those who believe that the earth is billions of years old.
Radiocarbon is not suitable for this purpose because it is only applicable: a) on a time scale of thousands of years and b) to remains of once-living organisms (with minor exceptions, from which rocks are excluded).
However, the reason for this is understood and the problem is restricted to only a few special cases, of which freshwater clams are the best-known example.By radiocarbon dating a piece of wood which has been dated by counting the annual growth rings of trees back to when that piece of wood grew, a calibration table can be constructed to convert radiocarbon years to true calendar years.Of course, the table, so constructed, will only give the correct calibration if the tree-ring chronology which was used to construct it had placed each ring in the true calendar year in which it grew.Long tree-ring chronologies are rare (there are only two that I am aware of which are of sufficient length to be of interest to radiocarbon) and difficult to construct.They have been slowly built up by matching ring patterns between trees of different ages, both living and dead, from a given locality.
If this water is in contact with significant quantities of limestone, it will contain many carbon atoms from dissolved limestone.